OK, this is a gross oversimplification/generalization, but...
Typicaly, you want to run the lowest octane you can that allows the most timing advance without detonation.
On a low compression NA engine, especially at altitude, this is most often 87.
If your owners manual says to use 87, using 91 is most likely to deminish performance.
Octane is basically, the amount of fire retardent in the gas. And you want the minimum amount possible to eliminate knocking.
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